There are axes and javelin-like throwing weapons. Try both, they behave in very different ways.
Javelins are fast, armor killers with reasonable angle but you need very precise and thoughtful aiming to hit consistently. You throw "exactly where you throw". If your weapon is a centimeter away from your target, you don't hit.
Axes on the other side, are slow, high damage but bad against tincans, have a terrible angle and thus short effective range. But their main advantage is the way the collision detection works for them. They are huge moving object when thrown, their size makes it very easy to hit people, especially heads. You can nearly use them only relying on gut feeling for drop and movement correction (at decent throwing range ofc.), they will hit "by themselves".