Well, theese are my favorites.
1-Claymore 11-Neon Genesis Evangelion.
2-Berserk 12-NHK ni youkoso
3-Samurai Champloo 13-Serial Experiments Lain
4-Black Lagoon 14-Hellsing
5-Cowboy Bebob 15-Full Metal Alchemist
6-Darker Than Black 16-Trigun
7-DeathNote
8-Elfen Lied
9-Ergo Proxy
10-Last Exile
Thats all for now, will add new things as i watch.